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This feature is also found in C3S pastes. The above list is not exclusive because other forms have also been described. 3 Bond Formation Cementitious materials such as gypsum, portland cement, magnesium oxychloride, and alumina cement form porous bodies and explanation for their mechanical properties should take into account the nature of the void spaces and the solid portion. If the solid part determines strength, then several factors should be considered including the rate of dissolution and solubility of the cement, the role of nuclei and their growth, chemical and physical nature of the products, energetics of the surface and interfacial bonds.

At ten days of hydration the strength values were ranked as follows by Beaudoin and Ramachandran: C 4AF > C3S > C2S > C3A. At fourteen days the relative values were in the order C3S > C4AF > C2S > C3A. The BogueLerch strength values both at ten and fourteen days were: C3S > C2S > C3A > C4AF. At one year, the corresponding values were C3S > C2S > C4AF > C3A (Beaudoin-Ramachandran) and C3S = C2S > C3A > C4AF (BogueLerch). Beaudoin and Ramachandran found that compressive strength vs. porosity curves on a semilog plot showed a linear relationship for all pastes (Fig.

33] Type I C-S-H, forming elongated or fibrous particles, occurs at early ages. The particles are also described as spines, acicular, aciculae, prismatic, rod-shaped, rolled sheet, or by other descriptions. They are a few micrometers long. Type II C-S-H is described as a reticular or honeycombed structure and forms in conjunction with Type I. It does not normally occur in a C3S or C2S paste unless it is 20 Analytical Techniques in Concrete Science and Technology formed in the presence of admixtures.

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